Synthesis of a functional polymer with pendent luminescent phenylenevinylene units through nitroxide-mediated free-radical polymerization

Synthesis of a functional polymer with pendent luminescent phenylenevinylene units through nitroxide-mediated free-radical polymerization

In this communication we report the synthesis and the efficient polymerization of a PPV trimer, 4‐tert‐buty1‐4′‐(4‐vinylstyryl)‐trans‐stilbene. By using the TEMPO (2,2,6,6‐tetramethylpiperidin‐1‐yloxy)‐mediated free‐radical polymerization method, the corresponding polymer was obtained in high yields...

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Veröffentlicht in:Macromolecular rapid communications. 1996-10, Vol.17 (10), p.693-702
Hauptverfasser: Moroni, Marc, Hilberer, Alain, Hadziioannou, Georges
Format: Artikel
Sprache:eng
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
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container_title Macromolecular rapid communications.
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creator Moroni, Marc
Hilberer, Alain
Hadziioannou, Georges
description In this communication we report the synthesis and the efficient polymerization of a PPV trimer, 4‐tert‐buty1‐4′‐(4‐vinylstyryl)‐trans‐stilbene. By using the TEMPO (2,2,6,6‐tetramethylpiperidin‐1‐yloxy)‐mediated free‐radical polymerization method, the corresponding polymer was obtained in high yields, with a fair molecular weight and a small polydispersity. The presence of phenylenevinylene units in the side chains of the polymer gives rise to efficient blue fluorescence which makes the material suitable for light emission applications.
doi_str_mv 10.1002/marc.1996.030171004
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Synthesis of a functional polymer with pendent luminescent phenylenevinylene units through nitroxide-mediated free-radical polymerization
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