Synthesis of a functional polymer with pendent luminescent phenylenevinylene units through nitroxide-mediated free-radical polymerization

In this communication we report the synthesis and the efficient polymerization of a PPV trimer, 4‐tert‐buty1‐4′‐(4‐vinylstyryl)‐trans‐stilbene. By using the TEMPO (2,2,6,6‐tetramethylpiperidin‐1‐yloxy)‐mediated free‐radical polymerization method, the corresponding polymer was obtained in high yields, with a fair molecular weight and a small polydispersity. The presence of phenylenevinylene units in the side chains of the polymer gives rise to efficient blue fluorescence which makes the material suitable for light emission applications.