Polymerization of styrenes carrying dendrons of the first, second and third generation

Polymerization of styrenes carrying dendrons of the first, second and third generation

The synthesis of styrene monomers 5(G‐1,2,3) with Fréchet‐type dendrons of the first, second and third generation, and their radically initiated polymerization to result in high molecular weight dendrimers 6(G‐1,2,3) are reported. First light‐scattering investigations using 6(G‐2) show that this pol...

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Veröffentlicht in:Macromolecular rapid communications. 1996-08, Vol.17 (8), p.517-527
Hauptverfasser: Neubert, Ingo, Amoulong-Kirstein, Evelin, Schlüter, A.-Dieter, Dautzenberg, Herbert
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Zusammenfassung:The synthesis of styrene monomers 5(G‐1,2,3) with Fréchet‐type dendrons of the first, second and third generation, and their radically initiated polymerization to result in high molecular weight dendrimers 6(G‐1,2,3) are reported. First light‐scattering investigations using 6(G‐2) show that this polymer is best described as a Gaussian chain.
ISSN:1022-1336
1521-3927
DOI:10.1002/marc.1996.030170804