Kinetics of the chemical polymerization of pyrrole by potassium hexacyanoferrate(III)

The kinetics of the chemical polymerization of pyrrole by potassium hexacyanoferrate(III) in water at 0°C was studied. The order of the reaction with respect to both pyrrole and potassium hexacyanoferrate(III) was determined to be 1 and 2,6, respectively. The rate constant k of the polymerization re...

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Veröffentlicht in:	Macromolecular chemistry and physics 1995-03, Vol.196 (3), p.825-832
Hauptverfasser:	STANKOVIC, R, LANINOVIC, V, STANKOVIC, S, JOVANOVIC, S, VOJNOVIC, M
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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Zusammenfassung:	The kinetics of the chemical polymerization of pyrrole by potassium hexacyanoferrate(III) in water at 0°C was studied. The order of the reaction with respect to both pyrrole and potassium hexacyanoferrate(III) was determined to be 1 and 2,6, respectively. The rate constant k of the polymerization reaction was found to be 2,25 · 10−4 (dm3 · mol−1)2,6 · s−1.
ISSN:	1022-1352 1521-3935
DOI:	10.1002/macp.1995.021960312