The agent of the autocatalytic thermal decomposition of aliphatic nitrate ester explosives

The agent of the autocatalytic thermal decomposition of aliphatic nitrate ester explosives

The condensed‐phase thermal decomposition of aliphatic nitrate ester explosives is generally autocatalytic. The object of this article is to show that the agent of the autocatalysis is not the product NO2, as is generally believed, but to suggest that it may be the product formaldehyde.

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Veröffentlicht in:International journal of chemical kinetics 1985-10, Vol.17 (10), p.1085-1090
1. Verfasser: Batten, J. J.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
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Beschreibung
Zusammenfassung:The condensed‐phase thermal decomposition of aliphatic nitrate ester explosives is generally autocatalytic. The object of this article is to show that the agent of the autocatalysis is not the product NO2, as is generally believed, but to suggest that it may be the product formaldehyde.
ISSN:0538-8066
1097-4601
DOI:10.1002/kin.550171005