The √t law in solid-phase reactions. Analysis of the hypothesis on rate constant distribution

The √t law in solid-phase reactions. Analysis of the hypothesis on rate constant distribution

The reaction C2H5 + O2 → C2H5O2 in glassy methanol‐d4 and the H‐atom ion by CH3, C2H5, and n‐C4H9 radicals in C2H5OH + C2D5OH and CD3CH2OH + C2D5OH glassy mixtures have been studied by electron spin resonance. The analysis of the dependence of the reaction rates on the concentration of O2 (oxidation...

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Veröffentlicht in:International journal of chemical kinetics 1981-08, Vol.13 (8), p.707-728
Hauptverfasser: Zaskul'nikov, V. M., Vyazovkin, V. L., Bol'shakov, B. V., Tolkatchev, V. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:The reaction C2H5 + O2 → C2H5O2 in glassy methanol‐d4 and the H‐atom ion by CH3, C2H5, and n‐C4H9 radicals in C2H5OH + C2D5OH and CD3CH2OH + C2D5OH glassy mixtures have been studied by electron spin resonance. The analysis of the dependence of the reaction rates on the concentration of O2 (oxidation) and C2H5OH, CD3CH2OH (H‐atom ion) has shown that the √t law is not conditioned by the existence of regions characterized by different rate constants.
ISSN:0538-8066
1097-4601
DOI:10.1002/kin.550130803