A new mechanism for the reaction of ozone with olefins

A mechanism for ozone–olefin reactions is developed that is consistent with the recent findings of several investigations. These findings suggest a reaction sequence leading to the production of fewer free radical species than has been assumed in the past. Computer simulations using the new mechanis...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:International journal of chemical kinetics 1979-04, Vol.11 (4), p.399-410
Hauptverfasser: Dodge, Marcia C., Arnts, Robert R.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A mechanism for ozone–olefin reactions is developed that is consistent with the recent findings of several investigations. These findings suggest a reaction sequence leading to the production of fewer free radical species than has been assumed in the past. Computer simulations using the new mechanism reproduce experimental results obtained from the ozonolysis of propylene in air.
ISSN:0538-8066
1097-4601
DOI:10.1002/kin.550110405