Very low-pressure pyrolysis (VLPP) of t-butylmethyl ether

Very low-pressure pyrolysis (VLPP) of t-butylmethyl ether

The thermal decomposition of t‐butylmethyl ether has been studied using the VLPP technique. The recommended Arrhenius parameters for the molecular elimination, reaction (1), are A(800°K) = 101 3, 9 sec−1 and Ea (800°K) = 59.0 ± 1.0 kcal/mole. No radical reactions occur under the conditions used. The...

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Veröffentlicht in:International journal of chemical kinetics 1974-09, Vol.6 (5), p.631-641
Hauptverfasser: Choo, Kwang Yul, Golden, David M., Benson, Sidney W.
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container_title International journal of chemical kinetics
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creator Choo, Kwang Yul
Golden, David M.
Benson, Sidney W.
description The thermal decomposition of t‐butylmethyl ether has been studied using the VLPP technique. The recommended Arrhenius parameters for the molecular elimination, reaction (1), are A(800°K) = 101 3, 9 sec−1 and Ea (800°K) = 59.0 ± 1.0 kcal/mole. No radical reactions occur under the conditions used. These parameters are in good agreement with earlier experimental work and with theoretical estimates of both A and E.
doi_str_mv 10.1002/kin.550060503
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title Very low-pressure pyrolysis (VLPP) of t-butylmethyl ether
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