Very low-pressure pyrolysis (VLPP) of t-butylmethyl ether

Very low-pressure pyrolysis (VLPP) of t-butylmethyl ether

The thermal decomposition of t‐butylmethyl ether has been studied using the VLPP technique. The recommended Arrhenius parameters for the molecular elimination, reaction (1), are A(800°K) = 101 3, 9 sec−1 and Ea (800°K) = 59.0 ± 1.0 kcal/mole. No radical reactions occur under the conditions used. The...

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Veröffentlicht in:International journal of chemical kinetics 1974-09, Vol.6 (5), p.631-641
Hauptverfasser: Choo, Kwang Yul, Golden, David M., Benson, Sidney W.
Format: Artikel
Sprache:eng
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Zusammenfassung:The thermal decomposition of t‐butylmethyl ether has been studied using the VLPP technique. The recommended Arrhenius parameters for the molecular elimination, reaction (1), are A(800°K) = 101 3, 9 sec−1 and Ea (800°K) = 59.0 ± 1.0 kcal/mole. No radical reactions occur under the conditions used. These parameters are in good agreement with earlier experimental work and with theoretical estimates of both A and E.
ISSN:0538-8066
1097-4601
DOI:10.1002/kin.550060503