Influence of colloid suspensions of humic acids on the alkaline hydrolysis of N-methyl-N-nitroso-p-toluene sulfonamide

Influence of colloid suspensions of humic acids on the alkaline hydrolysis of N-methyl-N-nitroso-p-toluene sulfonamide

The influence of humic substances (HSs) upon the alkaline hydrolysis of N‐methyl‐N‐nitroso‐p‐toluene sulfonamide has been studied. Important inhibition of hydrolysis reaction has been reported. This inhibition has been explained in terms of association of reactants to the humic substances. Kinetic r...

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Veröffentlicht in:International journal of chemical kinetics 2010-05, Vol.42 (5), p.316-322
Hauptverfasser: Astray, G., García-Río, L., Lodeiro, C., Mejuto, J. C., Moldes, O., Morales, J., Moyano, F.
Format: Artikel
Sprache:eng
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Zusammenfassung:The influence of humic substances (HSs) upon the alkaline hydrolysis of N‐methyl‐N‐nitroso‐p‐toluene sulfonamide has been studied. Important inhibition of hydrolysis reaction has been reported. This inhibition has been explained in terms of association of reactants to the humic substances. Kinetic results have been modeled using the micellar pseudophase model. © 2010 Wiley Periodicals, Inc. Int J Chem Kinet 42: 316–322, 2010
ISSN:0538-8066
1097-4601
DOI:10.1002/kin.20481