Temperature dependence of the Raman spectra of NaClO 4 in relation to the 581 K phase transition

Temperature dependence of the Raman spectra of NaClO 4 in relation to the 581 K phase transition

The evolution of the internal and external modes in the Raman spectra of NaClO 4 has been studied in the neighbourhood of the transition temperature, at 581 K. Large changes in the frequencies of the external modes with temperature have been observed. These changes can be explained in terms of a mod...

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Veröffentlicht in:Journal of Raman spectroscopy 1978-02, Vol.7 (1), p.1-6
Hauptverfasser: Toupry‐Krauzman, N., Poulet, H.
Format: Artikel
Sprache:eng
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Zusammenfassung:The evolution of the internal and external modes in the Raman spectra of NaClO 4 has been studied in the neighbourhood of the transition temperature, at 581 K. Large changes in the frequencies of the external modes with temperature have been observed. These changes can be explained in terms of a model based on the reorientation of the perchlorate ions.
ISSN:0377-0486
1097-4555
DOI:10.1002/jrs.1250070105