2-Chloro-1-phenylindene from 1,1-Dichloro-trans-2,3-diphenylcyclopropane

An indene derivative was isolated from the reaction of trans-stilbene and sodium trichloroacetate in diglyme and tetrachloroethylene. The chemical and spectral studies indicate that the product isolated is 2-chloro-1-phenylindene, which originated from 1,1-dichloro-trans-2,3-diphenylcyclopropane via...

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Veröffentlicht in:	Journal of pharmaceutical sciences 1972-08, Vol.61 (8), p.1216-1219
Hauptverfasser:	Magarian, Robert Armen, Melton, Stuart, Natarelli, Gerry
Format:	Artikel
Sprache:	eng
Schlagworte:	1,1-Dichloro-trans-2,3-diphenylcyclopropane—intermediate in the formation of 2-chloro-1-phenylindene from trans-stilbene and sodium trichloroacetate in diglyme and tetrachloro-ethylene 1-Dichloro-trans-2 2-chloro-1-phenylindene 2-Chloro-1-phenylindene-synthesis from trans-stilbene and sodium trichloroacetate in diglyme and tetrachloroethylene via 1 2-Chloro-1-phenylindene—synthesis from trans-stilbene and sodium trichloroacetate in diglyme and tetrachloroethylene via 1,1-dichloro-trans-2,3-diphenylcyclopropane 3-diphenylcyclopropane 3-diphenylcyclopropane-intermediate in the formation of 2-chloro-1-phenylindene from trans-stilbene and sodium trichloroacetate in diglyme and tetrachloro-ethylene Chemical Phenomena Chemistry Chlorine Chromatography, Thin Layer Cyclopropanes geometric isomers of stilbene Indenes - chemical synthesis Infrared Rays isolation and identification of 2-chloro-1-phenylindene Mass Spectrometry Models, Structural PMR identification of 2-chloro-1-phenylindene PMR spectroscopy-identification PMR spectroscopy—identification, 2-chloro-1-phenylindene Receptor theory-cyclopropyl rigid ring system Receptor theory—cyclopropyl rigid ring system, geometric isomers of stilbene, isolation and identification of 2-chloro-1-phenylindene Stilbenes trans-Stilbene reaction with sodium trichloroacetate-isolation trans-Stilbene reaction with sodium trichloroacetate—isolation, PMR identification of 2-chloro-1-phenylindene Ultraviolet Rays
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Beschreibung
Zusammenfassung:	An indene derivative was isolated from the reaction of trans-stilbene and sodium trichloroacetate in diglyme and tetrachloroethylene. The chemical and spectral studies indicate that the product isolated is 2-chloro-1-phenylindene, which originated from 1,1-dichloro-trans-2,3-diphenylcyclopropane via an ionized rearrangement.
ISSN:	0022-3549 1520-6017
DOI:	10.1002/jps.2600610809