Synthesis of deuterium-labelled polyoctylalkanes

Synthesis of deuterium-labelled polyoctylalkanes

The synthesis of specifically labelled 9‐d‐9‐octylheptadecane (1) and 9‐d‐9,10‐dioctyloctadecane (2) has been achieved using selective and specific deuterium labelling methods. The precursor to the latter compound, tetraoctyl ethene, has been achieved by a variant of the McMurry reaction which impro...

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Veröffentlicht in:Journal of labelled compounds & radiopharmaceuticals 1995-12, Vol.36 (12), p.1205-1213
Hauptverfasser: Bolton, Roger, Luff, Stefan, Sutcliffe, Leslie H.
Format: Artikel
Sprache:eng
Schlagworte:
Aliphatic compounds
Chemistry
Exact sciences and technology
McMurry reaction
Organic chemistry
Preparations and properties
Triethylsilyl deuteride
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Zusammenfassung:The synthesis of specifically labelled 9‐d‐9‐octylheptadecane (1) and 9‐d‐9,10‐dioctyloctadecane (2) has been achieved using selective and specific deuterium labelling methods. The precursor to the latter compound, tetraoctyl ethene, has been achieved by a variant of the McMurry reaction which improves upon recently published methods.
ISSN:0362-4803
1099-1344
DOI:10.1002/jlcr.2580361211