Carotenoids and Degraded Carotenoids, VIII - Synthesis of (+)-Dihydroactinidiolide, (+)- and (−)-Actinidiolide, (+)- and (−)-Loliolide as well as (+)- and (−)-Epiloliolide
Enantiomerically pure (S)‐2,4,4‐trimethyl‐2‐cyclohexen‐1‐ol (1) was efficiently converted into four degraded lactonic carotenoids: (S)‐dihydroactinidiolide (5), (S)‐actinidiolide (9), (6S,7aR)‐loliolide (11) and (6S,7aS)‐epiloliolide (12). (R)‐Actinidiolide (9), (6R,7aS)‐loliolide (11) and (6R,7aR)‐...
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Veröffentlicht in: | Liebigs Annalen der Chemie 1993-01, Vol.1993 (1), p.77-82 |
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container_title | Liebigs Annalen der Chemie |
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creator | Mori, Kenji Khlebnikov, Vladimir |
description | Enantiomerically pure (S)‐2,4,4‐trimethyl‐2‐cyclohexen‐1‐ol (1) was efficiently converted into four degraded lactonic carotenoids: (S)‐dihydroactinidiolide (5), (S)‐actinidiolide (9), (6S,7aR)‐loliolide (11) and (6S,7aS)‐epiloliolide (12). (R)‐Actinidiolide (9), (6R,7aS)‐loliolide (11) and (6R,7aR)‐epiloliolide (12) were also prepared from (R)‐1. |
doi_str_mv | 10.1002/jlac.199319930113 |
format | Article |
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(R)‐Actinidiolide (9), (6R,7aS)‐loliolide (11) and (6R,7aR)‐epiloliolide (12) were also prepared from (R)‐1.</description><identifier>ISSN: 0170-2041</identifier><identifier>EISSN: 1099-0690</identifier><identifier>DOI: 10.1002/jlac.199319930113</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Actinidiolide ; Carotenoids ; Epiloliolide ; Loliolide</subject><ispartof>Liebigs Annalen der Chemie, 1993-01, Vol.1993 (1), p.77-82</ispartof><rights>Copyright © 1993 WILEY‐VCH Verlag GmbH & Co. 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Chem</addtitle><description>Enantiomerically pure (S)‐2,4,4‐trimethyl‐2‐cyclohexen‐1‐ol (1) was efficiently converted into four degraded lactonic carotenoids: (S)‐dihydroactinidiolide (5), (S)‐actinidiolide (9), (6S,7aR)‐loliolide (11) and (6S,7aS)‐epiloliolide (12). (R)‐Actinidiolide (9), (6R,7aS)‐loliolide (11) and (6R,7aR)‐epiloliolide (12) were also prepared from (R)‐1.</description><subject>Actinidiolide</subject><subject>Carotenoids</subject><subject>Epiloliolide</subject><subject>Loliolide</subject><issn>0170-2041</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqFkEFOwzAQRS0EEqVwAHZetqIudmwnzQpVaSlBEUgUCjvLiR3qEpoqjlRyA9bchCtxEpoWUMUCFqOvmT__LT4AxwR3CcbO6SyTSZf4Pq0HE0J3QINg30fY9fEuaGDiYeRgRvbBgbUzjBkj3GmA90AWeannuVEWyrmCA_1YSKUV3DI6cBKGIURwXM3LqbbGwjyFrZM2GphppYpcJqWZG2XyzCjdWTtrWOvj9a2N-n-60eq8dqC0cKmzrNZfP8OFyb7fDsFeKjOrj760Ce7Oh7fBBYquR2HQj1BCHUyRJJLShPbc1EsTpRwpCdXcWe2Y-9LFvZjRlHuEMFd5caxowpxYKseVvEdSn9MmIBtuUuTWFjoVi8I8y6ISBIu6c1F3LrY7X2XONpmlyXT1f0BcRv3gFwFtCMaW-uWHIIsn4XrU4-L-aiT4eDJhgxsmHugncLCWbA</recordid><startdate>19930121</startdate><enddate>19930121</enddate><creator>Mori, Kenji</creator><creator>Khlebnikov, Vladimir</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19930121</creationdate><title>Carotenoids and Degraded Carotenoids, VIII - Synthesis of (+)-Dihydroactinidiolide, (+)- and (−)-Actinidiolide, (+)- and (−)-Loliolide as well as (+)- and (−)-Epiloliolide</title><author>Mori, Kenji ; Khlebnikov, Vladimir</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3203-a1a33c386f7fcdd2aa13e5286f059a608b43f571146d7bbd3c42bad26a581f953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Actinidiolide</topic><topic>Carotenoids</topic><topic>Epiloliolide</topic><topic>Loliolide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mori, Kenji</creatorcontrib><creatorcontrib>Khlebnikov, Vladimir</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Liebigs Annalen der Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mori, Kenji</au><au>Khlebnikov, Vladimir</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carotenoids and Degraded Carotenoids, VIII - Synthesis of (+)-Dihydroactinidiolide, (+)- and (−)-Actinidiolide, (+)- and (−)-Loliolide as well as (+)- and (−)-Epiloliolide</atitle><jtitle>Liebigs Annalen der Chemie</jtitle><addtitle>Liebigs Ann. Chem</addtitle><date>1993-01-21</date><risdate>1993</risdate><volume>1993</volume><issue>1</issue><spage>77</spage><epage>82</epage><pages>77-82</pages><issn>0170-2041</issn><eissn>1099-0690</eissn><abstract>Enantiomerically pure (S)‐2,4,4‐trimethyl‐2‐cyclohexen‐1‐ol (1) was efficiently converted into four degraded lactonic carotenoids: (S)‐dihydroactinidiolide (5), (S)‐actinidiolide (9), (6S,7aR)‐loliolide (11) and (6S,7aS)‐epiloliolide (12). (R)‐Actinidiolide (9), (6R,7aS)‐loliolide (11) and (6R,7aR)‐epiloliolide (12) were also prepared from (R)‐1.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/jlac.199319930113</doi><tpages>6</tpages></addata></record> |
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subjects | Actinidiolide Carotenoids Epiloliolide Loliolide |
title | Carotenoids and Degraded Carotenoids, VIII - Synthesis of (+)-Dihydroactinidiolide, (+)- and (−)-Actinidiolide, (+)- and (−)-Loliolide as well as (+)- and (−)-Epiloliolide |
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