Carotenoids and Degraded Carotenoids, VIII - Synthesis of (+)-Dihydroactinidiolide, (+)- and (−)-Actinidiolide, (+)- and (−)-Loliolide as well as (+)- and (−)-Epiloliolide

Carotenoids and Degraded Carotenoids, VIII - Synthesis of (+)-Dihydroactinidiolide, (+)- and (−)-Actinidiolide, (+)- and (−)-Loliolide as well as (+)- and (−)-Epiloliolide

Enantiomerically pure (S)‐2,4,4‐trimethyl‐2‐cyclohexen‐1‐ol (1) was efficiently converted into four degraded lactonic carotenoids: (S)‐dihydroactinidiolide (5), (S)‐actinidiolide (9), (6S,7aR)‐loliolide (11) and (6S,7aS)‐epiloliolide (12). (R)‐Actinidiolide (9), (6R,7aS)‐loliolide (11) and (6R,7aR)‐...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Liebigs Annalen der Chemie 1993-01, Vol.1993 (1), p.77-82
Hauptverfasser: Mori, Kenji, Khlebnikov, Vladimir
Format: Artikel
Sprache:eng
Schlagworte:
Actinidiolide
Carotenoids
Epiloliolide
Loliolide
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Enantiomerically pure (S)‐2,4,4‐trimethyl‐2‐cyclohexen‐1‐ol (1) was efficiently converted into four degraded lactonic carotenoids: (S)‐dihydroactinidiolide (5), (S)‐actinidiolide (9), (6S,7aR)‐loliolide (11) and (6S,7aS)‐epiloliolide (12). (R)‐Actinidiolide (9), (6R,7aS)‐loliolide (11) and (6R,7aR)‐epiloliolide (12) were also prepared from (R)‐1.
ISSN:0170-2041
1099-0690
DOI:10.1002/jlac.199319930113