Determination of inorganic anions in Kraft pulping liquors by capillary electrophoresis

Various sulfur containing anions (sulfate, sulfite, and thiosulfate) in Kraft pulping process liquors are determined by capillary electrophoresis. In addition, other inorganic anions (hydroxide, chloride, oxalate, carbonate) are analyzed with the developed method. Through optimization of the separation conditions it is possible to simultaneously determine these anionic species in pulping liquors with direct and indirect UV detection at 185, 214, and 254 nm. To ensure short separation times a migration of the anionic analytes in the same direction as the electroosmotic flow (co‐electroosmotic CE) is established by reversal of the electroosmotic flow with 1,5‐dimethyl‐1,5‐diazaundecamethylene polymethobromide (hexadimethrine bromide; HDB; polybrene™) which is added to the electrolyte as EOF modifier. The impact of acetonitrile as organic modifier to improve the selectivity of the anionic analytes is also investigated. The developed method is then applied to analyze and quantify various anions in pulping liquors (white and black liquors). By simultaneously determining the hydroxide concentration it is possible to calculate effective alkalinity and sulfidity with the measured concentrations without the need of volumetric methods.