Reactions of N ‐aryl‐1 H ‐benzotriazolyl‐1‐methanamines with allyl trimethylsilanes. A facile route to trialkylsilane tetrahydroquinolines
N ‐Aryl‐1 H ‐benzotriazolyl‐1‐methanamines 1 , easily accessible from the condensation of anilines with formaldehyde and benzotriazole, undergo Lewis acid assisted reactions with allyl trimethylsilanes to give 4‐(trimethylsilyl)methyl‐1,2,3,4‐tetrahydroquinolines 2 in good to high yields....
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| Veröffentlicht in: | Journal of heterocyclic chemistry 1999-03, Vol.36 (2), p.371-375 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | N
‐Aryl‐1
H
‐benzotriazolyl‐1‐methanamines
1
, easily accessible from the condensation of anilines with formaldehyde and benzotriazole, undergo Lewis acid assisted reactions with allyl trimethylsilanes to give 4‐(trimethylsilyl)methyl‐1,2,3,4‐tetrahydroquinolines
2
in good to high yields. |
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| ISSN: | 0022-152X 1943-5193 |
| DOI: | 10.1002/jhet.5570360207 |