Mechanism of retention of hydrocarbons in reservoir rocks. Role of polar compounds and effect of additives

Evidence is given for the involvement of hydrophobic interactions in the retention of hydrocarbons in oil fields. A prerequisite is that the surface of the reservoir rock has to be hydrophobic. This was obtained through adsorption of lipophilic polar compounds. The isotherms for the adsorption of dodecylamine hydrochloride and N ‐hexadecylpyridine hydrochloride were plotted. The treated quartz could take up large amounts of toluene. The relationships between some features of the isotherms and the retention phenomenon have been analysed. The effect of water‐structuring additives (e.g. LiF, CaCl 2 , NaF and guanidine hydrochloride) on the recovery of hydrocarbons was investigated by means of static and dynamic methods.