MgSiO 3 nanoparticle‐catalyzed 1,3‐dipolar cycloaddition reactions in the synthesis of novel spiroindane‐1,3‐diones derived from substituted chalcones
Employment of metal nanoparticles has been one of the most promising synthetic strategies for a number of chemical transformations. New spiroindane‐1,3‐diones were synthesized through [3 + 2] cycloaddition in moderate to high yields by a three‐component reaction of heterocyclic chalcone derivatives,...
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Veröffentlicht in: | Journal of the Chinese Chemical Society (Taipei) 2019-12, Vol.66 (12), p.1708-1712 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Employment of metal nanoparticles has been one of the most promising synthetic strategies for a number of chemical transformations. New spiroindane‐1,3‐diones were synthesized through [3 + 2] cycloaddition in moderate to high yields by a three‐component reaction of heterocyclic chalcone derivatives, ninhydrin, and sarcosine/L‐proline. The presence of heterogenous MgSiO
3
nanoparticles (NPs) under microwave irradiation showed a robust effect in improving the yield of the desired products. Furthermore, the catalyst may be recovered and reused without significant loss of activity. |
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ISSN: | 0009-4536 2192-6549 |
DOI: | 10.1002/jccs.201800445 |