Alkoxide-Accelerated [1,3] Sigmatropic Shift of Bicyclo[3.2.1]oct-6-en-2-ols to 8-endo-Hydroxybicyclo[3.3.0]oct-2-en-4-ones

Bicyclo[3.2.1]oct‐6‐en‐2‐ols 6 are shown to undergo [1,3] sigmatropic shift to afford 8‐endo‐hydroxy‐bicyclo[3.3.0]oct‐2‐en‐4‐ones 8 under the influence of potassium hydride.

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Veröffentlicht in:	Journal of the Chinese Chemical Society (Taipei) 1998-10, Vol.45 (5), p.649-653
Hauptverfasser:	Chen, Yeh-Long, Chang, Chi-Kang, Chang, Nein-Chen
Format:	Artikel
Sprache:	eng
Schlagworte:	3] sigmatropic shift Alkoxide-accelerated Alkoxide‐accelerated [1,3] sigmatropic shift Bicyclo[3.2.1]octenols Bicyclo[3.3.0]octenes
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creator	Chen, Yeh-Long Chang, Chi-Kang Chang, Nein-Chen
description	Bicyclo[3.2.1]oct‐6‐en‐2‐ols 6 are shown to undergo [1,3] sigmatropic shift to afford 8‐endo‐hydroxy‐bicyclo[3.3.0]oct‐2‐en‐4‐ones 8 under the influence of potassium hydride.
doi_str_mv	10.1002/jccs.199800098
format	Article
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subjects	3] sigmatropic shift Alkoxide-accelerated Alkoxide‐accelerated [1,3] sigmatropic shift Bicyclo[3.2.1]octenols Bicyclo[3.3.0]octenes
title	Alkoxide-Accelerated [1,3] Sigmatropic Shift of Bicyclo[3.2.1]oct-6-en-2-ols to 8-endo-Hydroxybicyclo[3.3.0]oct-2-en-4-ones
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