Alkoxide-Accelerated [1,3] Sigmatropic Shift of Bicyclo[3.2.1]oct-6-en-2-ols to 8-endo-Hydroxybicyclo[3.3.0]oct-2-en-4-ones

Alkoxide-Accelerated [1,3] Sigmatropic Shift of Bicyclo[3.2.1]oct-6-en-2-ols to 8-endo-Hydroxybicyclo[3.3.0]oct-2-en-4-ones

Bicyclo[3.2.1]oct‐6‐en‐2‐ols 6 are shown to undergo [1,3] sigmatropic shift to afford 8‐endo‐hydroxy‐bicyclo[3.3.0]oct‐2‐en‐4‐ones 8 under the influence of potassium hydride.

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Veröffentlicht in:Journal of the Chinese Chemical Society (Taipei) 1998-10, Vol.45 (5), p.649-653
Hauptverfasser: Chen, Yeh-Long, Chang, Chi-Kang, Chang, Nein-Chen
Format: Artikel
Sprache:eng
Schlagworte:
3] sigmatropic shift
Alkoxide-accelerated
Alkoxide‐accelerated [1,3] sigmatropic shift
Bicyclo[3.2.1]octenols
Bicyclo[3.3.0]octenes
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Zusammenfassung:Bicyclo[3.2.1]oct‐6‐en‐2‐ols 6 are shown to undergo [1,3] sigmatropic shift to afford 8‐endo‐hydroxy‐bicyclo[3.3.0]oct‐2‐en‐4‐ones 8 under the influence of potassium hydride.
ISSN:0009-4536
2192-6549
DOI:10.1002/jccs.199800098