Stereoselective Total Synthesis of Xestodecalactone C

A simple and highly efficient stereoselective total synthesis of xestodecalactone C (IIb), a polyketide natural product, was achieved (Scheme 2). The synthesis involved Keck's asymmetric allylation, a iodine‐induced electrophilic cyclization, and an intramolecular Friedel–Crafts acylation as ke...

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Veröffentlicht in:	Helvetica chimica acta 2009-09, Vol.92 (9), p.1866-1872
Hauptverfasser:	Rajesh, Karuturi, Suresh, Vangaru, Selvam, Jondoss Jon Paul, Bhujanga Rao, Chitturi, Venkateswarlu, Yenamandra
Format:	Artikel
Sprache:	eng
Schlagworte:	Cyclization reactions Friedel - Crafts acylation Keck's allylation Xestodecalactone C
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description	A simple and highly efficient stereoselective total synthesis of xestodecalactone C (IIb), a polyketide natural product, was achieved (Scheme 2). The synthesis involved Keck's asymmetric allylation, a iodine‐induced electrophilic cyclization, and an intramolecular Friedel–Crafts acylation as key steps.
doi_str_mv	10.1002/hlca.200900068
format	Article
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subjects	Cyclization reactions Friedel - Crafts acylation Keck's allylation Xestodecalactone C
title	Stereoselective Total Synthesis of Xestodecalactone C
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