Vicinal Diamination of Terminal Olefins

Vicinal Diamination of Terminal Olefins

The present publication describes an efficient and mild three‐step conversion of a terminal olefin 1 into the corresponding 1,2‐diamine 5. The sequence includes: azidoiodination, substitution with NaN3, and catalytic hydrogenolysis. The terminal 1,2‐diamine 5 was converted into its cis‐dichloroplati...

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Veröffentlicht in:Helvetica chimica acta 2005-06, Vol.88 (6), p.1486-1490
Hauptverfasser: Pfaendler, Hans Rudolf, Klingl, Alexander
Format: Artikel
Sprache:eng
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Zusammenfassung:The present publication describes an efficient and mild three‐step conversion of a terminal olefin 1 into the corresponding 1,2‐diamine 5. The sequence includes: azidoiodination, substitution with NaN3, and catalytic hydrogenolysis. The terminal 1,2‐diamine 5 was converted into its cis‐dichloroplatinum(II) complex 6.
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.200590119