Photochromic Properties of New Benzoindene‐Fused 2 H ‐Chromenes

The synthesis and the photochromic properties of new photochromic 6,7‐ and 7,8‐benzoindene annellated benzopyrans are described. When compared to parent indeno‐fused 2 H ‐chromenes (2 H ‐[1]benzopyrans), compounds 10 and 12 exhibit a significant bathochromic shift of maximum‐absorption wavelength, a...

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Veröffentlicht in:Helvetica chimica acta 2003-03, Vol.86 (3), p.570-578
Hauptverfasser: Martins, Cristina I., Coelho, Paulo J., Carvalho, Luis M., Oliveira‐Campos, Ana M. F., Samat, André, Guglielmetti, Robert
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis and the photochromic properties of new photochromic 6,7‐ and 7,8‐benzoindene annellated benzopyrans are described. When compared to parent indeno‐fused 2 H ‐chromenes (2 H ‐[1]benzopyrans), compounds 10 and 12 exhibit a significant bathochromic shift of maximum‐absorption wavelength, an increase in the colorability, and similar fading rates.
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.200390057