3‐Phenyl‐ D 3 ‐Trishomocuban‐4‐ol: Structure and Configuration

The crystal structure of 3‐phenyl‐ D 3 ‐trishomocuban‐4‐ol ( 4 ) was determined by X‐ray crystallography ( Fig. 1 ). Compound 4 was prepared from 8‐phenylpentacyclo[5.4.0.0 2,6 .0 3,10 .0 5,9 ]undecan‐8‐ol in acidic medium. This is a facile method to prepare substituted trishomocubanes with a specif...

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Veröffentlicht in:Helvetica chimica acta 1994-03, Vol.77 (2), p.543-546
Hauptverfasser: Carpy, Alain J. M., Oliver, Douglas W.
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal structure of 3‐phenyl‐ D 3 ‐trishomocuban‐4‐ol ( 4 ) was determined by X‐ray crystallography ( Fig. 1 ). Compound 4 was prepared from 8‐phenylpentacyclo[5.4.0.0 2,6 .0 3,10 .0 5,9 ]undecan‐8‐ol in acidic medium. This is a facile method to prepare substituted trishomocubanes with a specific configuration at C(4).
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.19940770215