Crystal Structure of Bis(η6-mesitylene)iron(II) Hexafluorophosphate

The crystal Structure of [Fe(η6‐mesitylene)2](PF6)2 (1) is reported. The Structure is intricately disordered with the Fe‐atom occupying an m3m cubic site, but nonetheless the conformation and bonding is confirmed. The structure is discussed in the general context of FeII sandwich complexes.

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Veröffentlicht in:Helvetica chimica acta 1992-02, Vol.75 (1), p.294-302
Hauptverfasser: Cameron, T. Stanley, Linden, Anthony, Sturge, K. Craig, Zaworotko, Michael J.
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal Structure of [Fe(η6‐mesitylene)2](PF6)2 (1) is reported. The Structure is intricately disordered with the Fe‐atom occupying an m3m cubic site, but nonetheless the conformation and bonding is confirmed. The structure is discussed in the general context of FeII sandwich complexes.
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.19920750126