Synthesis of 1 H ,2,3‐Triazoles from 2‐Substituted Cyclododecanones and Phenyl Azide

Synthesis of 1 H ,2,3‐Triazoles from 2‐Substituted Cyclododecanones and Phenyl Azide

By reaction with phenyl azide, 2‐cyano‐ and 2‐(ethoxycarbonyl)‐substituted cyclododecanones are converted into 5‐amino‐ and 5‐hydroxy‐1 H ‐1,2,3‐triazoles, respectively. The possible reaction mechanism is discussed.

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Veröffentlicht in:Helvetica chimica acta 1991-06, Vol.74 (4), p.899-903
Hauptverfasser: Ognyanov, Vassil I., Hesse, Manfred
Format: Artikel
Sprache:eng
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Zusammenfassung:By reaction with phenyl azide, 2‐cyano‐ and 2‐(ethoxycarbonyl)‐substituted cyclododecanones are converted into 5‐amino‐ and 5‐hydroxy‐1 H ‐1,2,3‐triazoles, respectively. The possible reaction mechanism is discussed.
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.19910740421