A Regiospecific Photochemical Rearrangement of 2-Azabenzotricyclo[5.2.2.01,5]- to 2-Azabenzotricyclo[6.2.1.01,5]undecatrienone

The 2‐azatricyclo[5.2.2.01,5]undeca‐4,8,10‐trien‐3‐ones 1a and 1b gave on irradiation the 2‐azatricyclo‐[6.2.1.01,5]undeca‐4,6,9‐trien‐3‐ones 2a and 2b, respectively. The rearrangement was found to be solvent‐, oxygen‐, and wavelength‐independant.

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Bibliographische Detailangaben
Veröffentlicht in:	Helvetica chimica acta 1989-05, Vol.72 (3), p.502-506
Hauptverfasser:	Trifonov, Latchezar S., Dimitrov, Valentin S., Orahovats, Alexander S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The 2‐azatricyclo[5.2.2.01,5]undeca‐4,8,10‐trien‐3‐ones 1a and 1b gave on irradiation the 2‐azatricyclo‐[6.2.1.01,5]undeca‐4,6,9‐trien‐3‐ones 2a and 2b, respectively. The rearrangement was found to be solvent‐, oxygen‐, and wavelength‐independant.
ISSN:	0018-019X 1522-2675
DOI:	10.1002/hlca.19890720313