The Thermal Reactivity of 5,8α-Epidioxy-5α-cholestan-3β-yl Acetate in Acetic Acid

The thermolysis of the steroidal 5α,8β‐peroxide 1, under acidic conditions afforded in addition to the expected 5,10:8,9‐diseco derivative 2, the rearranged 5α,8β‐epoxide 3, the structure of which was determined by NMR spectroscopy and X‐ray analysis.

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Bibliographische Detailangaben
Veröffentlicht in:	Helvetica chimica acta 1987-02, Vol.70 (1), p.37-42
Hauptverfasser:	Fuhrer, Hermann, Rihs, Grety, Lorenc, Ljubinka, Bondarenko, Lidija, Kalvoda, Jaroslav, Mihailović, Mihailo Lj
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Heterocyclic compounds Organic chemistry Organic compounds Physics Preparations and properties Steroids Structure of solids and liquids crystallography Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:	The thermolysis of the steroidal 5α,8β‐peroxide 1, under acidic conditions afforded in addition to the expected 5,10:8,9‐diseco derivative 2, the rearranged 5α,8β‐epoxide 3, the structure of which was determined by NMR spectroscopy and X‐ray analysis.
ISSN:	0018-019X 1522-2675
DOI:	10.1002/hlca.19870700104