Hydroboration and Oxymercuration of Some 1-Substituted Norborn-2-enes

The 1‐substituted norborn‐2‐enes 11–13 and 18 react with electrophiles under kinetic control preferentially in 2‐position. The regioselectivity in oxymercuration is higher than in hydroboration and reaction with aqueous palladium chloride.

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Bibliographische Detailangaben
Veröffentlicht in:	Helvetica chimica acta 1983, Vol.66 (8), p.2729-2739
Hauptverfasser:	Luef, Wolfgang, Vögeli, Ulrich-Christian, Keese, Reinhart
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The 1‐substituted norborn‐2‐enes 11–13 and 18 react with electrophiles under kinetic control preferentially in 2‐position. The regioselectivity in oxymercuration is higher than in hydroboration and reaction with aqueous palladium chloride.
ISSN:	0018-019X 1522-2675
DOI:	10.1002/hlca.19830660842