Über stereoselektive Synthesen und Reaktionen von 5,6‐Epoxy‐perhydroisoindolinen
Stereo‐selective syntheses of 2,5,6‐trisubstituted perhydroisoindolines are achieved by preparation of the three diastereoisomeric 5,6‐epoxy‐perhydroisoindolines and their reactions with nucleophiles, e.g. amines. The transformation of trans‐amino alcohols obtained in this way into cis‐amino alcohol...
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| Veröffentlicht in: | Helvetica chimica acta 1974-04, Vol.57 (3), p.572-585 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Stereo‐selective syntheses of 2,5,6‐trisubstituted perhydroisoindolines are achieved by preparation of the three diastereoisomeric 5,6‐epoxy‐perhydroisoindolines and their reactions with nucleophiles, e.g. amines. The transformation of trans‐amino alcohols obtained in this way into cis‐amino alcohols is described. |
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| ISSN: | 0018-019X 1522-2675 |
| DOI: | 10.1002/hlca.19740570311 |