Sythese von α und β‐Sinensal

Sythese von α und β‐Sinensal

β‐Sinensal (2,6‐dimethyl‐10‐methylene‐dodeca‐2,6,11‐trienal) was synthesized from the diene‐aldehyde 5. This was converted into the trans‐ and cis‐triene‐aldehydes 16 and 17, which were condensed with the phosphorane 18 to give the corresponding two geometrical isomers (3 and 19) of β‐sinensal....

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Veröffentlicht in:Helvetica chimica acta 1967, Vol.50 (8), p.2445-2456
Hauptverfasser: Bertele, E., Schudel, P.
Format: Artikel
Sprache:eng
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Zusammenfassung:β‐Sinensal (2,6‐dimethyl‐10‐methylene‐dodeca‐2,6,11‐trienal) was synthesized from the diene‐aldehyde 5. This was converted into the trans‐ and cis‐triene‐aldehydes 16 and 17, which were condensed with the phosphorane 18 to give the corresponding two geometrical isomers (3 and 19) of β‐sinensal.
ISSN:0018-019X
1522-2675
DOI:10.1002/hlca.19670500830