Solid state 13 C NMR can distinguish between bronsted and Lewis acid adducts of amines

Solid state 13 C NMR can distinguish between bronsted and Lewis acid adducts of amines

The solid 13 C NMR spectra of solid complexes of phenethylamine with SnCl 4, Me 3 SnCl, AlCl 3, and HCl are presented and discussed as a means of distinguishing between Bronsted and Lewis acid adducts of alkyl amines. Solution 13 C NMR results are discussed in terms of species present in complex equ...

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Veröffentlicht in:Heteroatom chemistry 1992-06, Vol.3 (3), p.235-238
Hauptverfasser: Ofori‐Okai, Gabriel, Bank, Shelton
Format: Artikel
Sprache:eng
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Zusammenfassung:The solid 13 C NMR spectra of solid complexes of phenethylamine with SnCl 4, Me 3 SnCl, AlCl 3, and HCl are presented and discussed as a means of distinguishing between Bronsted and Lewis acid adducts of alkyl amines. Solution 13 C NMR results are discussed in terms of species present in complex equilibria and their detection using the two NMR methods.
ISSN:1042-7163
1098-1071
DOI:10.1002/hc.520030307