Polyazaphosphorus macrocycles: Synthesis, reactivity, complexation
A general synthesis of various polyazaphosphorus macrocycles involving [1 + 1], [2 + 2], or [3 + 3] cyclocondensations is reviewed, as well as the attempted synthesis of cryptands. Selective reduction (imino functions) methylation (PS groups), silylation (PO groups) are reported. Preparations of s...
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Veröffentlicht in: | Heteroatom chemistry 1991-02, Vol.2 (1), p.45-54 |
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creator | Majoral, Jean-Pierre Badri, Meryam Caminade, Anne-Marie |
description | A general synthesis of various polyazaphosphorus macrocycles involving [1 + 1], [2 + 2], or [3 + 3] cyclocondensations is reviewed, as well as the attempted synthesis of cryptands. Selective reduction (imino functions) methylation (PS groups), silylation (PO groups) are reported. Preparations of some macrocycle complexes are described. |
doi_str_mv | 10.1002/hc.520020107 |
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title | Polyazaphosphorus macrocycles: Synthesis, reactivity, complexation |
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