Polyazaphosphorus macrocycles: Synthesis, reactivity, complexation

Polyazaphosphorus macrocycles: Synthesis, reactivity, complexation

A general synthesis of various polyazaphosphorus macrocycles involving [1 + 1], [2 + 2], or [3 + 3] cyclocondensations is reviewed, as well as the attempted synthesis of cryptands. Selective reduction (imino functions) methylation (PS groups), silylation (PO groups) are reported. Preparations of s...

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Veröffentlicht in:Heteroatom chemistry 1991-02, Vol.2 (1), p.45-54
Hauptverfasser: Majoral, Jean-Pierre, Badri, Meryam, Caminade, Anne-Marie
Format: Artikel
Sprache:eng
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Zusammenfassung:A general synthesis of various polyazaphosphorus macrocycles involving [1 + 1], [2 + 2], or [3 + 3] cyclocondensations is reviewed, as well as the attempted synthesis of cryptands. Selective reduction (imino functions) methylation (PS groups), silylation (PO groups) are reported. Preparations of some macrocycle complexes are described.
ISSN:1042-7163
1098-1071
DOI:10.1002/hc.520020107