Intramolecular C-thiocarbamoylation of aroxy(isothiocyanato)phosphonium salts

Intramolecular C-thiocarbamoylation of aroxy(isothiocyanato)phosphonium salts

Isothiocyanatophosphonium salts bearing an aroxy group at the phosphorus atom have been obtained for the first time. As found, these compounds undergo an intramolecular heterocyclization to give hitherto unknown benzoxazaphosphininethiones or cyanoiminophosphoranes, according to the nature of the su...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Heteroatom chemistry 2008-11, Vol.19 (7), p.667-670
Hauptverfasser: Smalii, R. V., Marchenko, A. P., Koidan, Y. N., Chaikovskaya, A. A., Pinchuk, A. M., Tolmachev, A. A.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Isothiocyanatophosphonium salts bearing an aroxy group at the phosphorus atom have been obtained for the first time. As found, these compounds undergo an intramolecular heterocyclization to give hitherto unknown benzoxazaphosphininethiones or cyanoiminophosphoranes, according to the nature of the substituents on the aryl ring. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:667–670, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20491
ISSN:1042-7163
1098-1071
DOI:10.1002/hc.20491