Rhodium-catalyzed coupling reactions of β- or α,β-substituted vinylpyridines with alkenes via CH bond activation

Rhodium-catalyzed coupling reactions of β- or α,β-substituted vinylpyridines with alkenes via CH bond activation

β‐ or α,β‐Substituted vinylpyridines react with 3,3‐dimethylbut‐1‐ene in the presence of Wilkinson catalyst [RhCl(PPh3)3] to give the corresponding alkylated products along with unusually isomerized products. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:346–350, 2002; Published online in Wiley...

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Veröffentlicht in:Heteroatom chemistry 2002, Vol.13 (4), p.346-350
Hauptverfasser: Lim, Yeong-Gweon, Kang, Jung-Bu, Lee, Kieseung, Kim, Yong Hae
Format: Artikel
Sprache:eng
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Zusammenfassung:β‐ or α,β‐Substituted vinylpyridines react with 3,3‐dimethylbut‐1‐ene in the presence of Wilkinson catalyst [RhCl(PPh3)3] to give the corresponding alkylated products along with unusually isomerized products. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:346–350, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10045
ISSN:1042-7163
1098-1071
DOI:10.1002/hc.10045