One-Pot Indium Iodide Mediated Synthesis of Chiral β-Seleno Amides and Selenocysteine Derivatives by Ring-Opening Reaction of 2-Oxazolines

A set of chiral β‐seleno amides were efficiently synthesized by a simple and efficient procedure involving a ring‐opening reaction of 2‐oxazoline with diorganyl dichalcogenides mediated by indium(I) iodide. As an application, the synthesis of selenocysteine derivatives was accomplished. (© Wiley‐VCH...

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Veröffentlicht in:European Journal of Organic Chemistry 2007-11, Vol.2007 (32), p.5327-5331
Hauptverfasser: Braga, Antonio L., Vargas, Fabrício, Galetto, Fábio Z., Paixão, Márcio W., Schwab, Ricardo S., Taube, Paulo S.
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Sprache:eng
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Zusammenfassung:A set of chiral β‐seleno amides were efficiently synthesized by a simple and efficient procedure involving a ring‐opening reaction of 2‐oxazoline with diorganyl dichalcogenides mediated by indium(I) iodide. As an application, the synthesis of selenocysteine derivatives was accomplished. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200700671