A Quantitative Investigation of the Water-Solubilizing Properties of Branched Oligoglycerols
Water solubility and partition‐coefficient measurements have been conducted on already known monobenzoylated octamethylenediamine‐containing branched oligoglycerols. A new oligoglycerol, a hexamer bearing eight primary hydroxy groups, has also been prepared and its properties examined. Water solubil...
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| Veröffentlicht in: | European Journal of Organic Chemistry 2007-06, Vol.2007 (18), p.3003-3011 |
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| container_end_page | 3011 |
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| container_issue | 18 |
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| container_title | European Journal of Organic Chemistry |
| container_volume | 2007 |
| creator | Nemoto, Hisao Araki, Takaaki Kamiya, Masaki Kawamura, Tomoyuki Hino, Tomoaki |
| description | Water solubility and partition‐coefficient measurements have been conducted on already known monobenzoylated octamethylenediamine‐containing branched oligoglycerols. A new oligoglycerol, a hexamer bearing eight primary hydroxy groups, has also been prepared and its properties examined. Water solubility was found to increase in an approximately geometric progression with the number of hydroxy groups and the water solubility of the hexamer derivative was atleast half a million times greater than that of the propanamide derivative. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) |
| doi_str_mv | 10.1002/ejoc.200601036 |
| format | Article |
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| ispartof | European Journal of Organic Chemistry, 2007-06, Vol.2007 (18), p.3003-3011 |
| issn | 1434-193X 1099-0690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_ejoc_200601036 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Glycerols Hydroxylation Iminodiacetic acid Oligomers Solvolysis |
| title | A Quantitative Investigation of the Water-Solubilizing Properties of Branched Oligoglycerols |
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