Diastereospecific Tandem Prins Cyclisation/Rearrangement Reactions for the Desymmetrisation of Cyclohexa-1,4-dienes

Diastereospecific Tandem Prins Cyclisation/Rearrangement Reactions for the Desymmetrisation of Cyclohexa-1,4-dienes

The Prins cyclisation has been used for the first time to desymmetrise a 1,4‐diene. Products derived from both normal Prins and rearrangement pathways were obtained, all with complete stereocontrol. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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Veröffentlicht in:European Journal of Organic Chemistry 2007-02, Vol.2007 (5), p.792-803
Hauptverfasser: Elliott, Mark C., El Sayed, Nahed N. E., Paine, James S.
Format: Artikel
Sprache:eng
Schlagworte:
Cyclohexadiene
Desymmetrisation
Prins reaction
Stereoselective
Wagner-Meerwein rearrangement
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Zusammenfassung:The Prins cyclisation has been used for the first time to desymmetrise a 1,4‐diene. Products derived from both normal Prins and rearrangement pathways were obtained, all with complete stereocontrol. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200600928