Towards the Total Synthesis of Vibsanin E, 15-O-Methylcyclovibsanin B,3-Hydroxyvibsanin E, Furanovibsanin A, and 3-O-Methylfuranovibsanin A

Studies detailing synthetic approaches to a variety of biosynthetically related vibsanin‐type diterpenes (i.e. vibsanin E, 15‐O‐methylcyclovibsanin B, 3‐hydroxy‐vibsanin E, furanovibsanin A, and 3‐O‐methylfuranovibsanin A) are discussed. Biogenetically modelled approaches are coupled with an investi...

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Veröffentlicht in:European Journal of Organic Chemistry 2006-07, Vol.2006 (14), p.3181-3192
Hauptverfasser: Schwartz, Brett D., Tilly, David P., Heim, Ralf, Wiedemann, Stefan, Williams, Craig M., Bernhardt, Paul V.
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Sprache:eng
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Zusammenfassung:Studies detailing synthetic approaches to a variety of biosynthetically related vibsanin‐type diterpenes (i.e. vibsanin E, 15‐O‐methylcyclovibsanin B, 3‐hydroxy‐vibsanin E, furanovibsanin A, and 3‐O‐methylfuranovibsanin A) are discussed. Biogenetically modelled approaches are coupled with an investigation of classical and modern six‐ to seven‐membered ring‐expansion protocols, which gain access to the central core of these natural products. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200600246