Enantioselective Synthesis of Thiosulfinates and of Acyclic Alkylidenemethylene Sulfide Sulfoxides

Enantioselective Synthesis of Thiosulfinates and of Acyclic Alkylidenemethylene Sulfide Sulfoxides

Enantioselectivities up to 75 % have been found in the catalytic mono‐oxidation of di‐tert‐butyl disulfide and related compounds as well as of ketene‐S,S‐acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined. (© Wiley‐VCH Verlag...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:European Journal of Organic Chemistry 2005-05, Vol.2005 (9), p.1727-1730
Hauptverfasser: Colonna, Stefano, Pironti, Vincenza, Drabowicz, Jozef, Brebion, Franck, Fensterbank, Louis, Malacria, Max
Format: Artikel
Sprache:eng
Schlagworte:
Asymmetric synthesis
Bovine serum albumin
Chiral dioxirane
Enantioselectivity
Thiosulfinate
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Enantioselectivities up to 75 % have been found in the catalytic mono‐oxidation of di‐tert‐butyl disulfide and related compounds as well as of ketene‐S,S‐acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200400892