A Stereoselective Synthesis of Five- and Six-Membered Cyclic β-Amino Acids

A Stereoselective Synthesis of Five- and Six-Membered Cyclic β-Amino Acids

The cyclic β‐amino acids 1 and 2 have been prepared in a short and stereoselective manner. The synthesis features a diastereoselective thioester enolate/imine condensation reaction and a ring‐closing metathesis as key processes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)...

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Veröffentlicht in:European journal of organic chemistry 2003-02, Vol.2003 (4), p.756-760
Hauptverfasser: Perlmutter, Patrick, Rose, Mark, Vounatsos, Filisaty
Format: Artikel
Sprache:eng
Schlagworte:
Amino acids
Asymmetric synthesis
Ring-closing metathesis
Thioester
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Zusammenfassung:The cyclic β‐amino acids 1 and 2 have been prepared in a short and stereoselective manner. The synthesis features a diastereoselective thioester enolate/imine condensation reaction and a ring‐closing metathesis as key processes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200390118