The First Hydroxysilylation of Alkenes with Triethylsilane under Dioxygen Catalyzed by N-Hydroxyphthalimide

The First Hydroxysilylation of Alkenes with Triethylsilane under Dioxygen Catalyzed by N-Hydroxyphthalimide

Catalytic hydroxysilylation of alkenes with trialkylsilane under dioxygen through a radical process was successfully achieved by the use of N‐hydroxyphthalimide (NHPI) as a catalyst under mild conditions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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Veröffentlicht in:European journal of organic chemistry 2003-06, Vol.2003 (12), p.2286-2289
Hauptverfasser: Tayama, Osamu, Iwahama, Takahiro, Sakaguchi, Satoshi, Ishii, Yasutaka
Format: Artikel
Sprache:eng
Schlagworte:
Alkene
Catalysts
Hydroxysilylation
Molecular oxygen
N-(Hydroxy)phthalimide
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Zusammenfassung:Catalytic hydroxysilylation of alkenes with trialkylsilane under dioxygen through a radical process was successfully achieved by the use of N‐hydroxyphthalimide (NHPI) as a catalyst under mild conditions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200300074