First Observation of NIR 4f-4f Luminescence through the Energy Transfer from the SOMO π Doublet in Nitronyl Nitroxide Radical Lanthanide(III) Complexes

First Observation of NIR 4f-4f Luminescence through the Energy Transfer from the SOMO π Doublet in Nitronyl Nitroxide Radical Lanthanide(III) Complexes

This study demonstrates the first observation of energy transfer from the doublet state of the nitronyl nitroxide radical ligand in LnIII complexes, exerting the light‐harvesting antenna effect on the NIR luminescence for the first time. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germa...

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Veröffentlicht in:European Journal of Inorganic Chemistry 2005-09, Vol.2005 (17), p.3503-3505
Hauptverfasser: Kaizaki, Sumio, Shirotani, Dai, Tsukahara, Yasunori, Nakata, Hiroyasu
Format: Artikel
Sprache:eng
Schlagworte:
Antenna effect
Energy transfer
Lanthanide(III) complexes
Near infrared 4f-4f luminescence
Nitronyl nitroxide radical
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Zusammenfassung:This study demonstrates the first observation of energy transfer from the doublet state of the nitronyl nitroxide radical ligand in LnIII complexes, exerting the light‐harvesting antenna effect on the NIR luminescence for the first time. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200500061