Copper-Catalysed Decarboxylative Trifluoromethylation of β-Ketoacids

Copper-Catalysed Decarboxylative Trifluoromethylation of β-Ketoacids

An efficient method for Cu-catalyzed decarboxylative trifluoromethylation offl-ketoacids to achieve a-trifluoro- methyl ketones was developed. A wide variety of synthetically useful α-trifluoromethyl ketones were obtained in modest to good yields under mild reaction conditions. The present method al...

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Veröffentlicht in:Chinese journal of chemistry 2017-11, Vol.35 (11), p.1665-1668
Hauptverfasser: Xu, Xiaolan, Chen, Huanhuan, He, Jianbo, Xu, Huajian
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Sprache:eng
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decarboxylative
trifluoromethylation
α‐trifluoromethyl ketones
β‐ketoacids
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container_end_page 1668
container_issue 11
container_start_page 1665
container_title Chinese journal of chemistry
container_volume 35
creator Xu, Xiaolan
Chen, Huanhuan
He, Jianbo
Xu, Huajian
description An efficient method for Cu-catalyzed decarboxylative trifluoromethylation offl-ketoacids to achieve a-trifluoro- methyl ketones was developed. A wide variety of synthetically useful α-trifluoromethyl ketones were obtained in modest to good yields under mild reaction conditions. The present method also exhibits good functional-group compatibility.
doi_str_mv 10.1002/cjoc.201700271
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source Wiley Online Library Journals Frontfile Complete
subjects decarboxylative
trifluoromethylation
α‐trifluoromethyl ketones
β‐ketoacids
title Copper-Catalysed Decarboxylative Trifluoromethylation of β-Ketoacids
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