Co 2 (CO) 8 ‐mediated Selective Reductions of Propargyl Alcohol Derivatives to Alkenes

Co 2 (CO) 8 ‐mediated Selective Reductions of Propargyl Alcohol Derivatives to Alkenes

In the presence of Co 2 (CO) 8 and additives, propargyl alcohol derivatives could be reduced to alkenes in moderate to good yield. The selectivity of this reaction could be controlled by adding different additives: with H 2 O as the additive, the major configuration of product is Z‐ alkene; with CF...

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Veröffentlicht in:Chinese journal of chemistry 2014-10, Vol.32 (10), p.999-1002
Hauptverfasser: Dou, Ying, Xing, Ping, Huang, Zuogang, Jiang, Biao
Format: Artikel
Sprache:eng
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Zusammenfassung:In the presence of Co 2 (CO) 8 and additives, propargyl alcohol derivatives could be reduced to alkenes in moderate to good yield. The selectivity of this reaction could be controlled by adding different additives: with H 2 O as the additive, the major configuration of product is Z‐ alkene; with CF 3 COOH as the additive, the major configuration of product is E ‐alkene.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201400396