A Convenient Hydrogenation Method for the Synthesis of Metallo‐mesoporphyrin IX Dimethyl Esters via Self‐catalyzed CoCl 2 ‐NaBH 4 Reagent System

A Convenient Hydrogenation Method for the Synthesis of Metallo‐mesoporphyrin IX Dimethyl Esters via Self‐catalyzed CoCl 2 ‐NaBH 4 Reagent System

A convenient protocol has been developed for the hydrogenation of metallo‐protoporphyrin IX dimethyl esters (MPPDMEs) to their mesoporphyrin analogues using CoCl 2 ‐NaBH 4 reagent system. Metallo‐porphyrin complexes were found to perform as self‐catalysts in this procedure. This method provides seve...

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Veröffentlicht in:Chinese journal of chemistry 2012-10, Vol.30 (10), p.2461-2465
Hauptverfasser: Xu, Shichao, Hu, Bingcheng, Hu, Tianjing, Wang, Huan, Huang, Xiuyou, Lou, Xingkun, Liu, Zuliang
Format: Artikel
Sprache:eng
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Zusammenfassung:A convenient protocol has been developed for the hydrogenation of metallo‐protoporphyrin IX dimethyl esters (MPPDMEs) to their mesoporphyrin analogues using CoCl 2 ‐NaBH 4 reagent system. Metallo‐porphyrin complexes were found to perform as self‐catalysts in this procedure. This method provides several advantages such as safe and simple procedure, short reaction time, high yields and low cost.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201200581