ChemInform Abstract: Enhancement of the Catalytic Activity of Chiral H 8 ‐BINOL Titanium Complexes by Introduction of Sterically Demanding Groups at the 3‐Position

ChemInform Abstract: Enhancement of the Catalytic Activity of Chiral H 8 ‐BINOL Titanium Complexes by Introduction of Sterically Demanding Groups at the 3‐Position

It is demonstrated that the activity of chiral titanium catalysts derived from H 8 ‐BINOL ligands in the enantioselective arylation of aldehydes is significantly enhanced by an increase of the size of the substituent at the 3‐position.

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Veröffentlicht in:ChemInform 2016-12, Vol.47 (52)
Hauptverfasser: Hayashi, Yasuki, Yamamura, Nobuaki, Kusukawa, Takahiro, Harada, Toshiro
Format: Artikel
Sprache:eng
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Zusammenfassung:It is demonstrated that the activity of chiral titanium catalysts derived from H 8 ‐BINOL ligands in the enantioselective arylation of aldehydes is significantly enhanced by an increase of the size of the substituent at the 3‐position.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201652038