ChemInform Abstract: Asymmetric Nitrocyclopropanation of α‐Substituted α,β‐Enals Catalyzed by Diphenylprolinol Silyl Ether for the Construction of All‐Carbon Quaternary Stereogenic Centers

ChemInform Abstract: Asymmetric Nitrocyclopropanation of α‐Substituted α,β‐Enals Catalyzed by Diphenylprolinol Silyl Ether for the Construction of All‐Carbon Quaternary Stereogenic Centers

The first step in the title reaction proceeds with good to excellent enantioselectivity and the cis‐isomer is generally the major one.

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Veröffentlicht in:ChemInform 2016-01, Vol.47 (4), p.no-no
Hauptverfasser: Hayashi, Yujiro, Yamazaki, Tatsuya, Nakanishi, Yuki, Ono, Tsuyoshi, Taniguchi, Tohru, Monde, Kenji, Uchimaru, Tadafumi
Format: Artikel
Sprache:eng
Schlagworte:
cyclopropanation reactions
cyclopropane derivatives
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
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Zusammenfassung:The first step in the title reaction proceeds with good to excellent enantioselectivity and the cis‐isomer is generally the major one.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201604063